On the electronic structure of exciplexes with aliphatic amines II

Abstract

In this contribution a theoretical model for the electronic structure of an exciplex with n-type donors is developed. The model is applied to the intramolecular exciplexes in which a parasubstituted phenyl acts as acceptor. This allows one to determine values for the emission maximum and the fluorescence rate constant which approach the experimental observed values of these quantities within the experimental error.