Journal of the American Chemical Society · 2013 · 639 citations · 14 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistryMaterials ChemistrySolid-state ChemistryBattery MaterialsConductive MaterialsIon-conducting MaterialsIonic ConductivityIonic ConductorsSolid-state ElectrolytesLithium Superionic ConductorsLithium-ion Battery MaterialsLithium-ion ConductivityLithium-ion ConductorsRaw Material SubstitutionRoom-temperature Solid ElectrolytesSuperionic Conductors
The reaction of Li2S and P2S5 with Li4[SnS4], a recently discovered, good Li(+) ion conductor, yields Li10SnP2S12, the thiostannate analogue of the record holder Li10GeP2S12 and the second compound of this class of superionic conductors with very high values of 7 mS/cm for the grain conductivity and 4 mS/cm for the total conductivity at 27 °C. The replacement of Ge by Sn should reduce the raw material cost by a factor of ~3.
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Use of the Stimulated Echo in NMR Diffusion Studies
J. E. Tanner · The Journal of Chemical Physics · 1970 · 1.6K citations