Macromolecular Rapid Communications · 2003 · 131 citations · 14 references
Natural SciencesChemistryPhysicsPolymer ChemistryPolymer EngineeringPolymer MaterialsPolymer Physical ChemistryPolymer PhysicsPolymer StructurePolymerization ChemistryPolymerization KineticsPolymerization Temperature EffectsActivation EnergyActivation Energy DeterminationArrhenius KineticsHyperbranched PolymersPolymer Branching AnalysisPolymerization Mechanism AnalysisTemperature DependenceTemperature Dependence Of Polymerization
Abstract Branched poly(butyl acrylate) was obtained from pulsed‐laser polymerizations carried out in bulk and in solution between −16 and 60 °C. The predominantly short branches are formed by backbiting. The Arrhenius temperature dependence of the backbiting rate is calculated, and the activation energy of this process was found to be remarkably higher than that of propagation. Branching thus increases with temperature leading to broader SEC traces and difficulties in the accurate determination of k p . Arrhenius plot of k fp2 versus 1/ T determined experimentally. magnified image Arrhenius plot of k fp2 versus 1/ T determined experimentally.
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