Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases · 1974 · 27 citations · 0 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistrySurface ChemistrySurface ScienceAdsorption At InterfacesAdsorption ProcessesSurface AdsorptionSurface PhysicsSurface ReactionsThermal DesorptionAdsorbent InteractionsAdsorption ChemistryAdsorption ReactionsAdsorption Thermodynamics
Adsorption potential calculations have been made for the adsorption of water onto ideal (100) and (110) faces of rutile. The results for the (110) face may be interpreted so as to be consistent with the published results of i.r. studies and temperature programmed desorption. The position in relation to the (100) face results remains unresolved. The effects of substituting Al3+ and Ti3+ for Ti4+ in the (110) surface plane have been investigated and predict a decrease in the adsorption potential of a water molecule.