Angewandte Chemie International Edition · 2015 · 289 citations · 38 references
Natural SciencesChemistryCrystal StructureInorganic ChemistryOrganic ChemistryCrystal ChemistryCrystallization ProcessesHeterocyclic ChemistryMolecular SymmetryPhotochemistrySupramolecular MaterialsChemical Bonding In CrystalsMolecular AggregationMolecular CrystalsOrganic CrystalsSpontaneous Emission
An o-carborane-based anthracene was synthesized, and single crystals, with incorporated solvent molecules, were obtained from the CHCl3 , CH2 Cl2 , and C6 H6 solutions. The anthracene ring in the crystal is highly distorted by the formation of a π-stacked dimer between the anthracene units. The crystals exhibited a variety of emission behaviors such as aggregation-induced emission (AIE), crystallization-induced emission (CIE), aggregation-caused quenching (ACQ), and multichromism.
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