Aqueous hypervalent silicon complexes with aliphatic sugar acids

Stephen D. Kinrade, Robin J. Hamilton, Andrew S. Schach, Christopher T. G. Knight

Journal of the Chemical Society Dalton Transactions · 2001 · 78 citations · 6 references

Concepts

Abstract

Silicon-29 and carbon-13 NMR spectroscopy is employed to determine the structures of stable five- and six-coordinated organosilicon complexes formed by the addition of certain aliphatic acid carbohydrates (such as gluconic acid, glucoheptonic acid and saccharic acid) to aqueous alkaline silicate solutions.

References

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