Journal of the Chemical Society Dalton Transactions · 2001 · 78 citations · 6 references
Natural SciencesBiochemistryChemistryCarbohydrate ChemistryInorganic ChemistryAcid-base ChemistryCoordination ChemistryBioinorganic Coordination ChemistryComplex Formation StudiesComplexation ChemistrySilicate ChemistrySilicate Tetrahedral CoordinationSilicon ChemistrySupramolecular Coordination Complexes
Silicon-29 and carbon-13 NMR spectroscopy is employed to determine the structures of stable five- and six-coordinated organosilicon complexes formed by the addition of certain aliphatic acid carbohydrates (such as gluconic acid, glucoheptonic acid and saccharic acid) to aqueous alkaline silicate solutions.
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Stable Five- and Six-Coordinated Silicate Anions in Aqueous Solution
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Iran Fattahpour Sedeh, Lars-Olof Öhman, Staffan Sjöberg et al. · Acta chemica Scandinavica/Acta chemica Scandinavica. B, Organic chemistry and biochemistry/Acta chemica Scandinavica. A, Physical and inorganic chemistry/Acta chemica Scandinavica. Series B. Organic chemistry and biochemistry/Acta chemica Scandinavica. Series A, Physical and inorganic chemistry · 1992 · 19 citations · Full text