Chemical Communications · 2015 · 80 citations · 29 references
Natural SciencesChemistryMaterials SciencePhysical ChemistrySurface ChemistrySurface ScienceChemical BondingNanostructured SurfacesPhotochemistrySurface ModificationSurface PhysicsSurface ReactivityGold Surface FunctionalizationMild Reaction ConditionsPhotochemical Bond CleavagePhotochemical FunctionalizationPhotochemical Surface ReactionsSurface OrderSurface SynthesisUllmann Coupling
The surface-assisted synthesis of gold-organometallic hybrids on the Au(111) surface both by thermo- and light-initiated dehalogenation of bromo-substituted tetracene is reported. Combined X-ray photoemission (XPS) and scanning tunneling microscopy (STM) data reveal a significant increase of the surface order when mild reaction conditions are combined with 405 nm light irradiation.
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Natural Sciences, Materials Engineering, Materials Science +14
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