Concepedia

Cationic Cyclopentadienyl Zinc Complexes with Slipped Triple‐Decker and Half‐Sandwich Structures

Maren A. Chilleck, Thomas Braun, Beatrice Braun

Chemistry - A European Journal · 2011 · 21 citations · 31 references

DOI

Concepts

Abstract

Giving zinc the slip! Cationic triple-decker zinc complexes [Zn2Cp*3]+ [BArF4]− (Cp*=C5Me5; BArF4= B(3,5-(CF3)2C6H3)4, B(C6F5)4; see scheme) were prepared by protonation of [ZnCp*2]. The cations adopt an unusual slipped triple-decker structure and can act as a source of a {ZnCp*}+ entity.

References

31

Single-crystal structure validation with the program<i>PLATON</i>

Anthony L. Spek · Journal of Applied Crystallography · 2003 · 13.9K citations · Full text

, , +16

Noncoordinating Anions—Fact or Fiction? A Survey of Likely Candidates

Ingo Krossing, Ines Raabe · Angewandte Chemie International Edition · 2004 · 1.1K citations · Full text

, , +17

[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2]+: a convenient reagent for generation and stabilization of cationic, highly electrophilic organometallic complexes

Maurice Brookhart, Barbara Grant, Angela Volpe · Organometallics · 1992 · 895 citations

, , +7

Decamethyldizincocene, a Stable Compound of Zn(I) with a Zn-Zn Bond

I. Resa, Ernesto Carmona, Enrique Gutiérrez‐Puebla et al. · Science · 2004 · 561 citations

, , +9

The (Me <sub>5</sub> C <sub>5</sub> )Si <sup>+</sup> Cation: A Stable Derivative of HSi <sup>+</sup>

Peter Jutzi, Andreas Mix, Britta Rummel et al. · Science · 2004 · 217 citations

, , +8