Concepedia

Chain Complexes with Eleven Metal Atoms

Simon J. Davies, Judith A. K. Howard, Rupert J. Musgrove, F. G. A. Stone

Angewandte Chemie International Edition in English · 1989 · 21 citations · 1 references

DOI

Concepts

Abstract

The linear Pt6W3Mo2 cluster 2 was obtained from the M3 complex 1 in a sequential manner using a rational procedure involving successive reaction with Pt(cod) and W  CR or Mo  CR as appropriate (R = p-tolyl). The structure of 2 was characterized.

References

1

Heteronuclear ‘Star Clusters’: [Ni<sub>2</sub>Pt<sub>2</sub>W<sub>4</sub>(μ<sub>3</sub>‐CPh)<sub>4</sub>(CO)<sub>8</sub>(η‐C<sub>5</sub>H<sub>5</sub>)<sub>4</sub>] and [Ni<sub>2</sub>Pt<sub>2</sub>W<sub>4</sub> (μ<sub>2</sub>‐CR)(μ<sub>3</sub>‐CR)<sub>3</sub>(CO)<sub>8</sub>(η‐C<sub>5</sub>H<sub>5</sub>)<sub>4</sub>] (R = Ph or <i>p</i>‐C<sub>6</sub>H<sub>4</sub>Me)

Gregory P. Elliott, Judith A. K. Howard, Takaya Mise et al. · Angewandte Chemie International Edition in English · 1986 · 21 citations

, , +14