Journal of the Chemical Society Chemical Communications · 1975 · 13 citations · 0 references
Natural SciencesChemistryPhysicsInorganic ChemistryPhysical ChemistryTheoretical ChemistryCoordination ChemistryCrystal ChemistryCrystal Field TheoryMetal-ligand BondingTransition Metal ChemistryTransition Metal ComplexesCrystal Field AnalysisCrystal Field Effects In Solid-state MaterialsCrystal-field EffectsElectronic Spectra Of Transition Metal ComplexesLigand Field EffectsMetal-ligand Bonding In Crystal FieldsSpectral Absorption BandsTetrahedral Coordination
The perturbation of the ligands by the metal ion, in contrast to the converse procedure of traditional crystal field theory, accounts satisfactory for the relatively strong d-electron absorption bands of the tetrahedral transition-metal tetrahalides.