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Olefin metatheses in metal coordination spheres: novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes
56
Citations
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References
2000
Year
Materials ScienceInorganic ChemistryChemical EngineeringEngineeringPlatinum ComplexesSquare-planar RhodiumCoordination ComplexNovel Trans-spanning BidentateMolecular ComplexCatalysisOlefin MetathesesChemistryOrganometallic CatalysisTrans Pph2Inorganic SynthesisMetal Coordination Spheres
The title reaction is applied to square-planar rhodium and platinum complexes with trans PPh2(CH2)6CHCH2 ligands, and square-planar platinum or octahedral tungsten complexes with trans or facial PPh[(CH2)6CHCH2]2 ligands. Ring-closing (poly)macrocyclizations occur.
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