Nickel‐Catalyzed CP Cross‐Coupling by CCN Bond Cleavage

Abstract

Prosperous coupling: A nickel-catalyzed CP cross-coupling reaction with Me3SiPPh2 by carbon–cyano bond cleavage has been developed. This method is characterized by its simplicity and wide application to the synthesis of various monophosphorus and P,N bidentate ligands (see scheme).