Self‐Assembly of Interpenetrating Coordination Nets Formed from Interpenetrating Cationic and Anionic Three‐Dimensional Diamondoid Cluster Coordination Polymers

Abstract

Tetrathiometalates [WS4]2− are the nodal building blocks in a new kind of heterometallic interpenetrating three-dimensional cluster coordination polymer (see picture) that has interesting nonlinear optical properties. The polymer exhibits optical self-focusing behavior and reverse saturable absorption effects. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2004/z460681_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.