Concepedia

Synthesis and Structure of a <i>rac</i>‐Tris(divinyldisiloxane) diplatinum(0) Complex and its Reaction with Maleic Anhydride

Peter B. Hitchcock, Michael F. Läppert, Nicholas J.W. Warhurst

Angewandte Chemie International Edition in English · 1991 · 195 citations · 4 references

DOI

Concepts

Abstract

rac-Tris(divinyldisiloxane)diplatinum(0) 1 is obtained on reaction of [Pt(cod)2] with tetramethyldivinyldisiloxane. Detailed multinuclear NMR studies showed that solutions of 1 are almost identical to the catalytically active solution which is used in the hydrosilation of unsaturated compounds.

References

4

A convenient and novel route to bis(.eta.-alkyne)platinum(0) and other platinum(0) complexes from Speier's hydrosilylation catalyst H2[PtCl6].xH2O. X-ray structure of [Pt{(.eta.-CH2=CHSiMe2)2O}(P-t-Bu3)]

G. Chandra, Peter Y. Lo, Peter B. Hitchcock et al. · Organometallics · 1987 · 185 citations

, , +13

X-ray and neutron diffraction studies of the crystal and molecular structures of tris(ethylene)platinum and bis(ethylene)(tetrafluoroethylene)platinum

Judith Howard, John L. Spencer, Sax A. Mason · Proceedings of the Royal Society of London A Mathematical and Physical Sciences · 1983 · 30 citations

, , +10

Bis(1,5-cyclooctadiene)platinum(0); X-ray structure at 200 K

J.A.K. Howard · Acta Crystallographica Section B · 1982 · 19 citations

, , +12

Fumarate, maleate and maleic anhydride complexes of platinum(O)

M.T. Chicote, Michael Green, John L. Spencer et al. · Journal of Organometallic Chemistry · 1977 · 13 citations

, , +4