Concepedia

Iron‐ and Cobalt‐Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands

Tomohiko Inagaki, Le Thanh Phong, Akihiro Furuta, Jun‐ichi Ito, Hisao Nishiyama

Chemistry - A European Journal · 2010 · 210 citations · 38 references

DOI

Concepts

Abstract

Chiral bis(oxazolinylphenyl)amines proved to be efficient auxiliary ligands for iron and cobalt catalysts with high activity for asymmetric hydrosilylation of ketones and asymmetric conjugate hydrosilylation of enones.

References

38

C2-Symmetric chiral bis(oxazoline)–metal complexes in catalytic asymmetric synthesis

Arun K. Ghosh, Mathivanan Packiarajan, John R. Cappiello · Tetrahedron Asymmetry · 1998 · 775 citations · Full text

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An Efficient and Chemoselective Iron Catalyst for the Hydrogenation of Ketones

Charles P. Casey, Hairong Guan · Journal of the American Chemical Society · 2007 · 530 citations

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Highly Efficient Catalyst Systems Using Iron Complexes with a Tetradentate PNNP Ligand for the Asymmetric Hydrogenation of Polar Bonds

C. Sui-Seng, Friederike Freutel, Alan J. Lough et al. · Angewandte Chemie International Edition · 2007 · 353 citations · Full text

, , +17

Efficient Asymmetric Transfer Hydrogenation of Ketones Catalyzed by an Iron Complex Containing a P−N−N−P Tetradentate Ligand Formed by Template Synthesis

Alexandre A. Mikhailine, Alan J. Lough, Robert H. Morris · Journal of the American Chemical Society · 2009 · 275 citations

, , +15

Cyclopentadienone Iron Alcohol Complexes: Synthesis, Reactivity, and Implications for the Mechanism of Iron-Catalyzed Hydrogenation of Aldehydes

Charles P. Casey, Hairong Guan · Journal of the American Chemical Society · 2009 · 271 citations · Full text

, , +16