Concepedia

Aminocyclopentadienes, Aminoferrocenes, and Aminocobaltocenes

Herbert Plenio, Dirk Burth

Angewandte Chemie International Edition in English · 1995 · 40 citations · 13 references

DOI

Concepts

Abstract

Good access to the title compounds is provided by the reaction shown below. Compound 1 reacts readily with secondary amines to give N,N-dialkylaminocyclopentadienes 2, whose Li salts can be treated, for example, with FeCl2 to give the ferrocene derivatives 3.

References

13

Derivatives of Dicyclopentadienyliron<sup>1</sup>

F. S. Arimoto, Alfred C. Haven · Journal of the American Chemical Society · 1955 · 400 citations

, , +5

Monosubstituted cyclopentadienyl half-sandwich transition metal complexes

Neil J. Coville, Karen E. du Plooy, Wolfgang Pickl · Coordination Chemistry Reviews · 1992 · 119 citations

, , +12

Redox-Switched Bonding of Protons to Ferrocenophanes, Ferrocene Cryptands, and Simple Ferrocene Amines. Correlation of X-ray Structural Data and Cyclic Voltammetry Derived Redox Potentials

Herbert Plenio, Jianjun Yang, Ralph Diodone et al. · Inorganic Chemistry · 1994 · 97 citations

, , +11

1,1′-Bis(N,N-dimethylamino)ferrocene,1,1′-bis(N,N-dimethylamino) cobaltocenium hexafluorophosphate and 1,1′-bis(N,N-dimethylamino)titanocene dichloride. Crystal structure of 1,1′-bis(N,N-dimethylamino)titanocene dichloride

Klaus-Peter Stahl, Gernot Boche, Werner Massa · Journal of Organometallic Chemistry · 1984 · 76 citations

, , +13

Cobalt complexes with the 1-[2-(N,N-dimethylamino)ethyl]-2,3,4,5-tetramethylcyclopentadienyl ligand

Peter Jutzi, Marc O. Kristen, Juergen Dahlhaus et al. · Organometallics · 1993 · 66 citations · Full text

, , +10