Angewandte Chemie International Edition · 2007 · 330 citations · 31 references
Natural SciencesChemistryMaterials ScienceHeat TransferInorganic ChemistryMaterials ChemistryThermal Expansion AnalysisThermal Properties Of MaterialsMetal-organic Framework AdsorptionMetal-organic FrameworksNegative Thermal ExpansionThermal ExpansionThermal Expansion EffectsThermal Expansion In MetalsThermal Expansion Modeling
Shrink when heated: A new model for flexible frameworks is used to simulate the structures and adsorption properties of isoreticular metal–organic frameworks (IRMOFs), such as IRMOF-1 (see picture; Zn silver, C cyan, H white, O red). The structural simulations suggest that the IRMOFs have negative thermalexpansion coefficients over their full temperature ranges of stability.
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Reticular synthesis and the design of new materials
Omar M. Yaghi, M. O’Keeffe, N.W. Ockwig et al. · Nature · 2003 · 9K citations
Natural Sciences, Materials Engineering, Materials Science +9
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
Hailian Li, Mohamed Eddaoudi, M. O’Keeffe et al. · Nature · 1999 · 8.4K citations · Full text