Pure and Applied Chemistry · 2008 · 23 citations · 32 references
Natural SciencesChemistryCatalysisOrganic ChemistryCarbonyl ChemistryCatalyst PreparationOrganic SynthesisCarbonylation Reactions
Abstract A new protocol for CO gas-free carbonylation, in which aldehydes are used as a substitute for CO, is described. The protocol consists of two Rh-mediated processes; the Rh-mediated decarbonylation of aldehydes, which leads to the formation of Rh carbonyl, and subsequent Rh-catalyzed carbonylative cyclization utilizing the in situ formed Rh carbonyl species.
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Progress in hydroformylation and carbonylation
Matthias Beller, B. Cornils, C.‐D. Frohning et al. · Journal of Molecular Catalysis A Chemical · 1995 · 872 citations