Die Makromolekulare Chemie · 1989 · 11 citations · 3 references
Natural SciencesChemistryMaterials ScienceOrganic ChemistryPolymer ChemistryPolymer MaterialsPolymer ProductionPolymerization ChemistryAromatic PolyamidesPerfluoroalkyl SubstancesPolycarboxylic AcidsSolubility
Abstract Trifluoromethyl‐, pentafluoroethyl‐ and other perfluoroalkylbenzenes ( 2a–d , 4 and 3 ) were prepared by the reaction of the corresponding aromatic halides with perfluorocarboxylic acids in the presence of copper(I) iodide. These products were modified by oxidation or (and) substitution reactions and subsequently polymerized to give perfluoroalkyl‐substituted polyamides, polyesters and poly(thio‐1,4‐phenylene)s showing good solubility.
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Synthesis of monomers and polymers by the Heck reaction
Walter Heitz, Wilhelm Brügging, Lothar Freund et al. · Die Makromolekulare Chemie · 1988 · 116 citations