A Well‐Defined Dinuclear Telluronic Acid [RTe(μ‐O)(OH)<sub>3</sub>]<sub>2</sub>

Jens Beckmann, Jens Bolsinger, Pamela Finke, Malte Hesse

Angewandte Chemie International Edition · 2010 · 28 citations · 18 references

Concepts

Abstract

Two for Te: The ditelluronic acid 3 is the first heavy congener of sulfonic and selenonic acids and is obtained by the O2 oxidation of the tellurinate 2 in the presence of [18]crown-6. Compound 2 is prepared by the reaction of the ditellurinic acid 1 with NaH. The direct oxidation of 1 to 3 using strong oxidants, such as H2O2, KMnO4, and NaIO4 failed.

References

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