Chemical Communications · 2013 · 50 citations · 26 references
Crystal StructureEngineeringPhysicsCubic Dipole LatticeNatural SciencesCarbon CagesHydrogen BondHydrogen-bonded LiquidCaged Water MoleculesPhysical ChemistryInterfacial StudyComputational ChemistryChemistryQuantum ChemistryHydrogenWater MoleculesCrystallographyCrystal Structure Design
We report the crystal structure and dielectric properties of a pure H2O@C60 crystal at low temperature. The caged water molecules free from the hydrogen bonds rotate even at 8 K. The antifreeze rotating water molecules respond to an external electric field due to their permanent dipole moment.
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Crystal structure and bonding of ordered C60
William I. F. David, R.M. Ibberson, J. C. Matthewman et al. · Nature · 1991 · 980 citations
Materials Science, Inorganic Chemistry, Crystal Structure +4