Recueil des Travaux Chimiques des Pays-Bas · 1953 · 14 citations · 10 references
Natural SciencesChemistryInorganic ChemistryPhysical ChemistryTheoretical ChemistryCoordination ChemistryMetal StabilityMetal-ligand BondingTransition Metal ChemistryTransition Metal ComplexesComplexation ChemistryElectronic Structure Of Metal ComplexesIonizationIonization StatesMetal Ion ChemistryMetal Ion StabilityMetal Ligand CoordinationStability Constants
Abstract The relation between the stability (log k) of a metal complex in solution and the ionization potential (I) of the metal component is ascertained for a number of systems described in the literature. There proves to be a linear relation of the following form: log k = p. (I − q). The value of q is found to depend on the functional group(s) of the ligand, that of p on the number of the functional groups in the ligand and the polarizability of the ligand molecule.
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Order of Stability of Metal Complexes
H. M. N. H. Irving, Richard J. Williams · Nature · 1948 · 1.2K citations
Jannik Bjerrum, Erling Juhl Nielsen, Niilo Rautanen et al. · Acta chemica Scandinavica/Acta chemica Scandinavica. B, Organic chemistry and biochemistry/Acta chemica Scandinavica. A, Physical and inorganic chemistry/Acta chemica Scandinavica. Series B. Organic chemistry and biochemistry/Acta chemica Scandinavica. Series A, Physical and inorganic chemistry · 1948 · 86 citations · Full text
Lars Gunnar Sillén, H. Viervoll, Lars Gunnar Sillén · Acta chemica Scandinavica/Acta chemica Scandinavica. B, Organic chemistry and biochemistry/Acta chemica Scandinavica. A, Physical and inorganic chemistry/Acta chemica Scandinavica. Series B. Organic chemistry and biochemistry/Acta chemica Scandinavica. Series A, Physical and inorganic chemistry · 1949 · 67 citations · Full text