Concepedia

How is Phosphorus Bound in 2‐Phospha‐ and 2‐“Phosphoniaallyl” Cations?

Roberta O. Day, Angela Willhalm, Joan M. Holmes, Robert R. Holmes, Alfred Schmidpeter

Angewandte Chemie International Edition in English · 1985 · 31 citations · 3 references

DOI

Concepts

Abstract

The conjugation in the 2-phosphaallyl cation 1 is removed upon methylation to the doubly positively charged species 2, a phosphane with two cationic substituents.

References

3

1<i>H</i>‐1,2,4‐Diazaphospholes via 2‐Phosphaallyl Chlorides

Alfred Schmidpeter, Angela Willhalm · Angewandte Chemie International Edition in English · 1984 · 63 citations

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2‐Phosphaallyl Cations by Formal Insertion of P<sup>⊕</sup> into the CC Double Bond

Alfred Schmidpeter, Siegfried Lochschmidt, Angela Willhalm · Angewandte Chemie International Edition in English · 1983 · 60 citations

, , +6

A New, Facile Route to 2‐Azaallenium Salts—Bis(2‐adamantylidene)ammonium Hexachloroantimonate

E.‐U. Würthwein, Rainer Kupfer, Peter H. M. Budzelaar et al. · Angewandte Chemie International Edition in English · 1985 · 15 citations

, , +8