Concepedia

Syntheses and magnetic properties of hexanuclear [Cp<sub>2</sub>Mn<sub>3</sub>(L<sub>1</sub>)<sub>4</sub>]<sub>2</sub>and octanuclear [Mn<sub>8</sub>(L<sub>2</sub>)<sub>12</sub>(μ<sub>4</sub>-O)<sub>2</sub>] (L<sub>1</sub>= 2-HNC<sub>5</sub>H<sub>5</sub>N, L<sub>2</sub>= 2-NH-3-Br-5-MeC<sub>5</sub>H<sub>3</sub>N, Cp = C<sub>5</sub>H<sub>5</sub>)

C.S. Alvarez, Andrew D. Bond, D. Cave, Marta E. G. Mosquera, E.A. Harron, Richard A. Layfield, Mary McPartlin, Jeremy M. Rawson, Paul T. Wood, Dominic S. Wright

Chemical Communications · 2002 · 35 citations · 17 references

DOI

Concepts

Abstract

The reactions of manganocene, Cp2Mn, with 2-aminopyridine (L1H) or 2-amino-3-bromo-5-methylpyridine (L2H) give the novel hexanuclear and octanuclear Mn(II) amido cage compounds [Cp2Mn3(L1)4]2 (1) and [Mn8(L2)12(mu 4-O)2] (2); magnetic measurements on which provide a rare insight into the magnetic properties of amido-bridged metal clusters.

References

17

Redetermination of the crystal structure of dimanganese decacarbonyl and determination of the crystal structure of dirhenium decacarbonyl. Revised values for the manganese-manganese and rhenium-rhenium bond lengths in dimanganese decacarbonyl and dirhenium decacarbonyl

Melvyn Rowen Churchill, Kwame N. Amoh, Harvey J. Wasserman · Inorganic Chemistry · 1981 · 269 citations

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Three coordination in metal complexes

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Manganese carboxylate clusters: from structuralaesthetics to single-molecule magnets

Guillem Arom, Sheila M. J. Aubin, M.A. Bolcar et al. · Polyhedron · 1998 · 183 citations

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Three-coordinate metal amides of manganese(II) and cobalt(II): synthesis and x-ray structure of the first tris(silylamide) of manganese and the x-ray crystal structures of [M2(N(SiMe3)2)4] (M = Mn, Co)

Brendan D. Murray, Philip P. Power · Inorganic Chemistry · 1984 · 139 citations

, , +10

Tetranuclear and Octanuclear Manganese Carboxylate Clusters:  Preparation and Reactivity of (NBu<sup>n</sup><sub>4</sub>)[Mn<sub>4</sub>O<sub>2</sub>(O<sub>2</sub>CPh)<sub>9</sub>(H<sub>2</sub>O)] and Synthesis of (NBu<sup>n</sup><sub>4</sub>)<sub>2</sub>[Mn<sub>8</sub>O<sub>4</sub>(O<sub>2</sub>CPh)<sub>12</sub>(Et<sub>2</sub>mal)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>] with a “Linked-Butterfly” Structure

Michael W. Wemple, Hui-Lien Tsai, Sheyi Wang et al. · Inorganic Chemistry · 1996 · 129 citations

, , +17