Concepedia

S<sub>7</sub>NH and S<sub>7</sub>NCH<sub>3</sub> as Novel Chelating Ligands in [(η<sup>5</sup>‐C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>Ti] Complexes: Synthesis of Medium‐Sized Sulfur–Nitrogen Rings by Ligand Transfer

Klaus Bergemann, Monika Kustos, Per Krüger, Ralf Steudel

Angewandte Chemie International Edition in English · 1995 · 16 citations · 8 references

DOI

Concepts

Abstract

The insertion of titanocene, prepared from the corresponding dicarbonyl complex, into SS bonds of S7NH and S7NMe affords the complexes 1 and 2, respectively, which are suitable as precursors for large SN rings. The treatment of 2 with SCl2 and S2Cl2 yields the imides S8NMe and S9NMe, respectively.

References

8

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Giuseppe Fachinetti, Carlo Floriani · Journal of the Chemical Society Dalton Transactions · 1974 · 34 citations

, , +8

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Alan Shaver, Stephen Morris · Inorganic Chemistry · 1991 · 19 citations

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