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U.V.‐Visible and Electron Spin Resonance Spectroelectrochemical Studies of Sulfur Oxidation in AlCl3 ‐ NaCl (63/37 m/o) Melt
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1981
Year
Materials ScienceTemperature Range 132°–250°CEngineeringOxidation ResistanceFundamental ElectrochemistryElectrode Reaction SequenceSpectroelectrochemistryAlcl3 ‐ NaclCatalysisChemistryDesulfurizationElectrochemical ResultsSulfur OxidationElectrode Reaction MechanismElectrochemistry
The electrooxidation of sulfur in molten (63‐37 mole percent) has been investigated by means of u.v.‐visible and electron spin resonance spectroelectrochemistry in the temperature range 132°–250°C. The electrode reaction sequence for the oxidation of to that was proposed previously based solely on electrochemical results has been modified to include several other intermediates, such as , , , and S (II).