Concepedia

Na<sub>2</sub>Ti<sub>3</sub>Cl<sub>8</sub>: From Isolated Ti<sup>2+</sup> Ions to [Ti<sub>3</sub>]<sup>6+</sup> Clusters

Dirk Hinz, G. Joel Meyer, Thorsten Dedecke, Werner Urland

Angewandte Chemie International Edition in English · 1995 · 28 citations · 5 references

DOI

Concepts

Abstract

Na2Ti3Cl8 is a temperature-dependent magnetic switch. The switching process (= phase transition) takes places below room temperature and is accompanied by a drastic decrease in magnetic susceptibility and molar volume. The transition is attributed to the formation of [Ti3]6+ clusters (see diagram) by two-dimensional Peierl's distortion within [TiCl4/2Cl2/3]2− layers.

References

5

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The crystal structure of Na<sub>6</sub>MnCl<sub>8</sub> and Na<sub>2</sub>Mn<sub>3</sub>Cl<sub>8</sub> and some isostructural compounds

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Ionic Conductivity, Structural, IR and Raman Spectroscopic Data of Olivine, Sr <sub>2</sub> PbO <sub>4</sub> , and Na <sub>2</sub> CuF <sub>4</sub> Type Lithium and Sodium Chlorides Li <sub>2</sub> ZnCl <sub>4</sub> and Na <sub>2</sub> MCl <sub>4</sub> (M = Mg, Ti, Cr, Mn, Co, Zn, Cd)

H. D. Lutz, K. Wussow, P. Kuske · Zeitschrift für Naturforschung B · 1987 · 35 citations · Full text

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Equilibria between Titanium Metal and Solutions of Titanium Dichloride in Fused Sodium Chloride

Kurt L. Komarek, P. Herasymenko · Journal of The Electrochemical Society · 1958 · 18 citations · Full text

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