Temperature-induced racemic compounds and chiral conglomerates based on polyoxometalates and lanthanides: syntheses, structures and catalytic properties

Abstract

Four new species, originated from [Co₂Mo₁₀H₄O₃₈]⁶⁻ and lanthanides by adjusting the reaction temperature, are reported, which act as Lewis acid–base catalysts toward the cyanosilylation reaction.