CrystEngComm · 2009 · 71 citations · 79 references
Natural SciencesChemistryMaterials ScienceCrystal StructureMagnetic MaterialsMaterials ChemistryAntiferromagnetic MaterialsCoordination ChemistryCrystal EngineeringMagnetic NanomaterialsMagnetic Properties Of SolidsMagnetism Of Inorganic CompoundsCoordination Compound MagnetismMagnetic Exchange PathwaysMagnetic Properties Of Coordination ComplexesMagnetic Properties Of Transition Metal ComplexesMagnetism Of Transition Metal ComplexesMetal-organic FrameworksMolecular MagnetismSupramolecular Networks
We present an overview of very recent advances in the engineering of magnetic networks based on octacyanometalates. The selected magnetic networks of CuIIWV, NiIIWV and MnIILNbIV (L – organic bridging linker) illustrate the possible strategies for tuning of the magnetic characteristics. The combination of magnetic ordering for 2D (two-dimensional) and 3D (three-dimensional) networks together with the solvent sensitivity of a cyano-bridged framework resulted in the development of a novel 3D {[MnII(imH)]2[NbIV(CN)8]} assembly with magnetic sponge character, characterized by Tc of 62 K, the highest ever observed for octacyanometalate-based networks.
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