One‐, Two‐, and Three‐Electron Reduction of a Cyclic Alkyl(amino)carbene–SbCl₃ Adduct

Abstract

A cyclic alkyl(amino)carbene readily reacts with SbCl3 to form the corresponding Sb(III) adduct. One-electron reduction gives rise to the first example of a neutral antimony-centered radical characterized in solution. Two-electron reduction affords a Lewis base stabilized chloro-stibinidene, whereas three-electron reduction gives an antimony diatomic species capped by two carbenes. The radical has been characterized by EPR spectroscopy, while the structure of the other three species has been ascertained by single-crystal X-ray diffraction. In these four species, the formal oxidation state of the metalloid diminishes from III, to II, to I, and finally 0.