Zeitschrift für anorganische und allgemeine Chemie · 2009 · 116 citations · 19 references
Natural SciencesChemistryCrystal StructureInorganic ChemistryMetallic MaterialsCoordination ChemistryMetal-ligand BondingMetallic BondingMetalsTransition Metal ChemistryTransition Metal ComplexesBonding In Coordination CompoundsCovalency In Metal-ligand BondsMetal Ligand CoordinationMetal-ligand Bond LengthMetal-ligand Bond OrderMetal-metal InteractionsMetalloid Complexes
Abstract The synthesis and structure of a homobimetallic chromium complex is reported. The ligand used to stabilise the quintuply bonded metals is a sterically fine‐tuned guanidinate. A chromium–chromium bond length of 1.7293(12) Å was observed. It is the shortest metal–metal distance reported for a stable compound yet.
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Synthesis of a Stable Compound with Fivefold Bonding Between Two Chromium(I) Centers
Tailuan Nguyen, Andrew D. Sutton, M. Brynda et al. · Science · 2005 · 562 citations · Full text
Electronic structure and vibrational frequency of Cr2
V. E. Bondybey, J. H. English · Chemical Physics Letters · 1983 · 231 citations
Natural Sciences, Chemistry, Physics +14