Influence of Catalyst Structure and Reaction Conditions on <i>anti</i>‐ versus <i>syn</i>‐Aminopalladation Pathways in Pd‐Catalyzed Alkene Carboamination Reactions of <i>N</i>‐Allylsulfamides

Abstract

The Pd-catalyzed coupling of N-allylsulfamides with aryl and alkenyl triflates to afford cyclic sulfamide products is described. In contrast to other known Pd-catalyzed alkene carboamination reactions, these transformations may be selectively induced to occur by way of either anti- or syn-aminopalladation mechanistic pathways by modifying the catalyst structure and reaction conditions.