Concepedia

Novel synthesis of enamines by iridium-catalyzed dehydrogenation of tertiary aminesElectronic supplementary information (ESI) available: detailed experimental procedures and spectroscopic information. See http://www.rsc.org/suppdata/cc/b3/b304357f/

Xiawei Zhang, Amy K. Fried, Spencer Knapp, Alan S. Goldman

Chemical Communications · 2003 · 129 citations · 9 references

DOI

Concepts

Abstract

A novel route to enamines is reported, the dehydrogenation of tertiary amines catalyzed by a "pincer-ligated" iridium catalyst.

References

9

Dehydrogenation of <i>n</i>-Alkanes Catalyzed by Iridium “Pincer” Complexes:  Regioselective Formation of α-Olefins

Fu‐Chen Liu, Esther B. Pak, Bharat Singh et al. · Journal of the American Chemical Society · 1999 · 318 citations

, , +13

Catalytic Dehydrogenation of Cycloalkanes to Arenes by a Dihydrido Iridium P−C−P Pincer Complex

Mukta Gupta, Chrystel Hagen, William C. Kaska et al. · Journal of the American Chemical Society · 1997 · 258 citations

, , +12

Variable regiochemistry in the stoichiometric and catalytic hydroamination of alkynes by imidozirconium complexes caused by an unusual dependence of the rate law on alkyne structure and temperature

Anne M. Baranger, Patrick J. Walsh, Robert G. Bergman · Journal of the American Chemical Society · 1993 · 202 citations

, , +9

Mechanism of Alkane Transfer-Dehydrogenation Catalyzed by a Pincer-Ligated Iridium Complex

Kenton B. Renkema, Yury V. Kissin, Alan S. Goldman · Journal of the American Chemical Society · 2003 · 149 citations

, , +14

Intramolecular aminopalladation and cross coupling of acetylenic amines

Fen‐Tair Luo, Ren‐Tzong Wang · Tetrahedron Letters · 1992 · 48 citations

, , +11