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Pulse and AC Impedance Studies of the Electrochemical Systems of Titanium in LiCl ‐ KCl Eutectic Melt at 743 K
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1988
Year
EngineeringElectrode-electrolyte InterfaceAc Impedance StudiesChemical EngineeringCorrosionEutectic MeltSolidificationElectrochemical InterfaceMaterials ScienceMaterials EngineeringElectrical EngineeringSolid-state IonicSurface ElectrochemistryPulse TechniquesElectrochemistryAc Impedance MeasurementsElectrochemical SystemsApplied PhysicsFundamental Electrochemistry
The electrochemistry of titanium in the eutectic melt has been investigated by means of pulse techniques and ac impedance measurements. The Ti3+/Ti(IV) electrochemical system appears reversible while Ti2+/Ti3+ is quasi reversible and metallic titanium deposition from Ti2+ is irreversible. Kinetic constants related to these redox systems have been determined, as have the thickness of the diffusion layer, the double layer capacitance, and the electrolyte resistance.