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Substitution reaction of triphenylphosphine oxide with rare-earth metal phosphido methyl complexes
15
Citations
14
References
2015
Year
Inorganic ChemistryChemical EngineeringSubstitution ReactionBond CleavageEngineeringCoordination ComplexOrganometallic CatalysisCatalysisMolecular ComplexChemistryBond FormationInorganic SynthesisTriphenylphosphine OxideInorganic Compound
Rare-earth metal phosphido methyl complexes [<bold>L</bold>Ln(Me){P(H)Ar}] react with triphenylphosphine oxide to give [<bold>L</bold>Ln(Ph){CH<sub>2</sub>P(O)Ph<sub>2</sub>}], indicating C(alkyl)–P bond formation and C(aryl)–P bond cleavage.
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