A Self-Assembled Porphyrin Box from mesomeso-Linked Bis{5-p-pyridyl-15-(3,5-di-octyloxyphenyl)porphyrinato zinc(II)} - Concepedia

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A Self-Assembled Porphyrin Box from mesomeso-Linked Bis{5-p-pyridyl-15-(3,5-di-octyloxyphenyl)porphyrinato zinc(II)}

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References

2002

Year

Akihiko Tsuda, Takeshi Nakamura, Shigeru Sakamoto, Kentaro Yamaguchi, Atsuhiro Osuka

Angewandte Chemie International Edition

Porphyrin SubunitsEngineeringMetal-organic PolyhedronRigorous Perpendicular OrientationOrganic ChemistryBox CleverCoordination PolymerChemistrySupramolecular ChemistryBiophysicsSelf-assembled Porphyrin BoxHost-guest Chemistry

Abstract

Box clever: A very stable box-shaped cyclic tetramer (see picture) was formed from meso-pyridyl substituted meso–meso-linked zinc(II) diporphyrin, in which the porphyrin subunits are held in a rigorous perpendicular orientation.