Study of Intermolecular Interactions in the Corrole Matrix by Solid‐State NMR under 100 kHz MAS and Theoretical Calculations

Abstract

A combination of solid-state NMR techniques and theoretical calculations confirmed that unsubstituted metal-free corroles form supramolecular systems with toluene through π–π interactions in the solid state. Ultrafast magic angle spinning (MAS) enabled the use of 1H–1H homonuclear correlation spectroscopy to explore those intermolecular interactions for which heteronuclear correlation methods were difficult to apply. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.