Publication | Closed Access
Initial reduction of CO<sub>2</sub> on perfect and O-defective CeO<sub>2</sub> (111) surfaces: towards CO or COOH?
44
Citations
59
References
2015
Year
Hydrogen ProductionWhereas Reductive DissociationEngineeringHydrogen TransitionSurface ScienceApplied PhysicsCatalysisChemistryHydrogenO-defective SurfaceTowards CoHydrogen GenerationInitial Reduction
CO<sub>2</sub> hydrogenation towards COOH is more favorable on perfect CeO<sub>2</sub> (111) surface, whereas reductive dissociation of CO<sub>2</sub> is predominant on O-defective surface. The O vacancy promotes reductive dissociation of CO<sub>2</sub> on O-defective CeO<sub>2</sub> (111) surface.
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