A Spherical 24 Butyrate Aggregate with a Hydrophobic Cavity in a Capsule with Flexible Pores: Confinement Effects and Uptake–Release Equilibria at Elevated Temperatures

Abstract

Forced interaction: The encapsulation of a large assembly of organic species—the 24 butyrate unit, which exhibits a remarkable central spherical hydrophobic cavity spanned by 72 H atoms—in a porous capsule (see picture) leads to interesting interactions between the butyrates under the confined conditions. The quarantine for the guests is lifted upon temperature increase: guests can easily leave and return. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.