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One-pot synthesis of high-molecular-weight aliphatic polycarbonates via melt transesterification of diphenyl carbonate and diols using Zn(OAc)<sub>2</sub> as a catalyst
42
Citations
39
References
2015
Year
Materials ScienceDiphenyl CarbonateChemical EngineeringEngineeringAliphatic PolycarbonatesSustainable SynthesisOrganic ChemistryCatalysisHomogeneous CatalysisChemistryMelt TransesterificationCatalyst PreparationHigh-molecular-weight Aliphatic PolycarbonatesOne-pot Melt TransesterificationCatalytic SynthesisPolymers
Aliphatic polycarbonates with <italic>M</italic><sub>w</sub> greater than 100 000 g mol<sup>−1</sup> with satisfactory yield can be synthesized by one-pot melt transesterification of diphenyl carbonate with aliphatic diols at equimolar amounts using Zn(OAc)<sub>2</sub> as a catalyst.
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