Enantioselective Aziridination and Amination Using <i>p</i>-Toluenesulfonyl Azide in the Presence of Ru(salen)(CO) Complex

Abstract

Abstract (R,R)-Ru(salen)(CO) complex (1) was found to catalyze enantioselective aziridination of conjugated terminal olefins and allylic C–H amination of conjugated olefins bearing geminal- and/or trans-substituent(s) in the presence of p-toluenesulfonyl azide.