Concepedia

Enantioselective Aziridination and Amination Using <i>p</i>-Toluenesulfonyl Azide in the Presence of Ru(salen)(CO) Complex

Kazufumi Omura, Masakazu Murakami, Tatsuya Uchida, Ryo Irie

Chemistry Letters · 2003 · 130 citations · 16 references

DOI

Concepts

Abstract

Abstract (R,R)-Ru(salen)(CO) complex (1) was found to catalyze enantioselective aziridination of conjugated terminal olefins and allylic C–H amination of conjugated olefins bearing geminal- and/or trans-substituent(s) in the presence of p-toluenesulfonyl azide.

References

16

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Bis(oxazoline)-copper complexes as chiral catalysts for the enantioselective aziridination of olefins

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Mechanism of the (Diimine)copper-Catalyzed Asymmetric Aziridination of Alkenes. Nitrene Transfer via Ligand-Accelerated Catalysis

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Copper-catalyzed aziridination of olefins by (N-(p-toluenesulfonyl)imino)phenyliodinane

David A. Evans, Margaret M. Faul, Mark T. Bilodeau · The Journal of Organic Chemistry · 1991 · 376 citations

, , +14