Concepedia

Thienyl carboxylate ligands bound to M2 quadruple bonds involving molybdenum and tungsten. Models for dimetallated polythiophenes

Matthew J. Byrnes, Malcolm H. Chisholm

Chemical Communications · 2002 · 28 citations · 4 references

DOI

Concepts

Abstract

Thienyl-carboxylate and -dicarboxylate groups attached to dinuclear centers (M = Mo or W) having MM quadruple bonds show interesting electronic properties and provide insight into the probable nature of related dimetallated polythiophenes.

References

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Transition-Metal-Polythiophene Hybrid Materials

Michael O. Wolf · Advanced Materials · 2001 · 203 citations

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Metal-metal multiple bonds in ordered assemblies. 1. Tetranuclear molybdenum and tungsten carboxylates involving covalently linked metal-metal quadruple bonds. Molecular models for subunits of one-dimensional stiff-chain polymers

Roger H. Cayton, Malcolm H. Chisholm, John C. Huffman et al. · Journal of the American Chemical Society · 1991 · 185 citations

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Oxalate-Bridged Complexes of Dimolybdenum and Ditungsten Supported by Pivalate Ligands:  (<sup>t</sup>BuCO<sub>2</sub>)<sub>3</sub>M<sub>2</sub>(μ-O<sub>2</sub>CCO<sub>2</sub>)M<sub>2</sub>(O<sub>2</sub>C<sup>t</sup>Bu)<sub>3</sub>. Correlation of the Solid-State, Molecular, and Electronic Structures with Raman, Resonance Raman, and Electronic Spectral Data

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