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Model complexes for ligand probes of met-hemocyanin and met-tyrosinase derivatives. Structure of a novel 1,1-azido bridged binuclear copper(II) complex
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1983
Year
EngineeringLigand ProbesMolecular BiologyChemistryNovel µ-1,1-Bridging ModeInorganic CompoundBioorganometallic ChemistryBiological Inorganic ChemistryAzide DerivativeInorganic ChemistryMet-tyrosinase DerivativesBiochemistryModel ComplexesBiological SystemsMolecular ModelingStructural BiologyNatural SciencesCoordination ComplexMolecular Complex
Addition of HX (X = N3–, Cl–) to a hydroxy-bridged binuclear copper(II) complex gives X-bridged complexes with an environment analogous to protein binuclear sites; the structure of the azide derivative shows a novel µ-1,1-bridging mode, suggesting this as a possibility in the biological systems.