Advanced Materials · 2005 · 127 citations · 24 references
Natural SciencesBiochemistryMaterials ScienceCrystal StructureMineralogyStructural BiologyCalcium-binding ProteinsCrystal ChemistryCrystal GrowthCrystallization ProcessesMineral GrowthCalcite MineralogyCalcium-binding Proteins In BiomineralizationCrystal Growth ControlCrystal Growth KineticsIon AttachmentKinetics Of Mineral GrowthMineral Growth ProcessesProtein-crystal Interactions
Abalone shell nacre proteins act as surfactants to promote ion attachment at calcite steps, causing acceleration of the molecular-scale kinetics of calcite crystal growth. The proteins modify the shape of growing calcite (see Figure) through step-specific interactions, even though the proteins are larger than the atomic-scale steps. Understanding of crystal-growth control by interactions with proteins may give better control of new crystalline materials.
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The Role of Mg <sup>2+</sup> as an Impurity in Calcite Growth
Kevin J. Davis, Patricia M. Dove, James J. De Yoreo · Science · 2000 · 731 citations