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Switching Regioselectivity in Crossed Acyloin Condensations between Aromatic Aldehydes and Acetaldehyde by Altering <i>N</i>-Heterocyclic Carbene Catalysts
91
Citations
30
References
2011
Year
Chemical EngineeringCross-coupling ReactionAromatic AldehydesN-heterocyclic Carbene CatalystsEngineeringHeterocyclicAlkene MetathesisOrganic ChemistryCrossed Acyloin CondensationsOrganometallic CatalysisCatalysisChemistryAppropriate ChoiceAcyloin CondensationsBiomolecular Engineering
An unprecedented high level of regioselectivities (up to 96%) in the intermolecular crossed acyloin condensations of various aromatic aldehydes with acetaldehyde was realized by an appropriate choice of N-heterocyclic carbene catalysts.
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