Langmuir · 1999 · 675 citations · 18 references
EngineeringFluid MechanicsBiomedical EngineeringSoft MatterEmulsionFluid PropertiesCapillarity PhenomenonPolymer ProcessingRheologyMonodisperse Emulsion GenerationParticle-laden FlowPhysicsDisperse FlowMultiphase FlowContinuous PhaseCoflowing StreamExperimental TechniqueDrop SizeMicroemulsionInterfacial PhenomenaDrop Break Off
We describe an experimental technique for the production of highly monodisperse emulsions (with minimum achievable polydispersities <3%). The phase to be dispersed is introduced into a coflowing, surfactant-laden continuous phase via a tapered capillary. Drops detach from the capillary when the streamwise forces exceed the force due to interfacial tension. Drop size is a function of the capillary tip diameter, the velocity of the continuous phase, the extrusion rate, and the viscosities and interfacial tension of the two phases. Emulsions composed of a variety of fluids and with drop sizes ranging from 2 to 200 μm have been produced using this technique.
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Ordered macroporous materials by emulsion templating
Arnout Imhof, David J. Pine · Nature · 1997 · 1.1K citations