Rheological behavior of blends of natural rubber and styrene–butadiene rubber latices

Abstract

Abstract The rheological behavior of blends of natural rubber (NR) and styrene–butadiene rubber (SBR) latices has been studied with reference to the effects of blend ratio, shear rate, surface‐active agents (casein and sodium carboxymethyl cellulose), and temperature. When the SBR content was less than 50%, the viscosities of the blends appeared to be a nonadditive function of the viscosities of the constituent homopolymers; i.e., a positive deviation was observed. This was due to the structural buildup of the SBR domains. The SBR domains underwent agglomeration and consequently so‐called microflocculation took place. The viscosities of all the blends were found to decrease with increase of temperature and shear rate. The increase in temperature and shear rate marginally weakened the structural buildup as evidenced by the lowering of viscosity. As the SBR content in the system increased, the pseudoplasticity of the blend increased. Even in the presence of surface‐active agents the blends showed composition‐dependent positive deviation. However, surface‐active agents marginally reduced the extent of structural buildup by reducing the microflocculation behavior of SBR domains. © 1995 John Wiley & Sons, Inc.