Peptide-metal complex as an asymmetric catalyst. A catalytic enantioselective cyanonhydrin synthesis.

Highly enantioselective borane reduction of ketones catalyzed by chiral oxazaborolidines. Mechanism and synthetic implications

E. J. Corey, Raman K. Bakshi, Saizo Shibata · Journal of the American Chemical Society · 1987 · 1.4K citations

Natural Sciences, Chemistry, Biocatalysis +10

Asymmetric synthesis of bicyclic intermediates of natural product chemistry

Zoltan G. Hajos, David R. Parrish · The Journal of Organic Chemistry · 1974 · 1.2K citations

Natural Sciences, Chemistry, Analytical Chemistry +9

Bis(oxazolines) as chiral ligands in metal-catalyzed asymmetric reactions. Catalytic, asymmetric cyclopropanation of olefins

David A. Evans, K. A. Woerpel, Mira M. Hinman et al. · Journal of the American Chemical Society · 1991 · 964 citations

Natural Sciences, Chemistry, Catalysis +10

Designed catalyst for enantioselective Diels-Alder addition from a C2-symmetric chiral bis(oxazoline)-iron(III) complex

E. J. Corey, Nobuyuki Imai, Hong Yue Zhang · Journal of the American Chemical Society · 1991 · 442 citations

Natural Sciences, Chemistry, Catalysis +15

Catalytic asymmetric induction. Highly enantioselective addition of dialkylzincs to aldehydes using chiral pyrrolidinylmethanols and their metal salts

Kenso Soai, Atsuhiro Ookawa, Tatsuya Kaba et al. · Journal of the American Chemical Society · 1987 · 329 citations

Natural Sciences, Chemistry, Biocatalysis +7