Chemical Communications · 2006 · 93 citations · 15 references
Natural SciencesChemical EngineeringChemistryGreen ChemistryOrganic ChemistryPolymer ChemistryGreen Polymer ChemistryMicrowave-assisted SynthesisPolymerization ChemistryPolymerization KineticsPolymerization ProcessesRing-opening PolymerizationIonic LiquidsIonic Ring-opening PolymerizationLiving Ring-opening PolymerizationMicrowave Irradiation EffectsMicrowave-assisted Organic SynthesisOxazole ChemistryPolymerization Rate ControlReaction Kinetics Under Microwave Irradiation
The living cationic ring opening polymerization of 2-ethyl-2-oxazoline performed in an ionic liquid under microwave irradiation showed an enhanced polymerization rate in comparison to the reaction in common organic solvents; the ionic liquid was efficiently recovered and reused in new reaction cycles, completely avoiding the use of organic volatile compounds.
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Frank Wiesbrock, Richard Hoogenboom, Mark A.M. Leenen et al. · Macromolecules · 2005 · 283 citations
Maggel Deetlefs, Kenneth R. Seddon · Green Chemistry · 2003 · 208 citations