Publication | Closed Access
“Supersilyl” Compounds (R<sub>3</sub>Si)<sub>3</sub>SiSi(SiR<sub>3</sub>)<sub>3</sub> and (R<sub>3</sub>Si)<sub>3</sub>SiC<sub>6</sub>H<sub>4</sub>Si(SiR<sub>3</sub>)<sub>3</sub>: Structures and Properties
63
Citations
17
References
1993
Year
Materials EngineeringInorganic ChemistryMaterials ScienceOrganosilicon CompoundsEngineeringSisi3 FrameworksTheoretical Inorganic ChemistryNatural SciencesRadical (Chemistry)Molecular BiologyEsr/endor SpectroscopyOrganic ChemistryMain Group ChemistryChemistrySupramolecular ChemistryInorganic MaterialNuclear Magnetic Resonance Spectroscopy
Remarkable properties characterize organosilicon compounds like 1 and 2: some of their structures are distorted by steric overcrowding and their first ionization energies drop as a result of additional radical cation stabilization to unexpectedly low values. In the π-radical anion of 2 considerable spin delocalization in the SiSi3 frameworks is detected by ESR/ENDOR spectroscopy.
| Year | Citations | |
|---|---|---|
Page 1
Page 1